Identify of Seawater Intrusion Using Hydrochemical Approach and Fuzzy Logic for the Ain Zara, Libya.

Authors

  • Khairi ’Mohamed Alamari Department Environmental Science & Engineering, Libyan Academy
  • Ahmed Ibrahim Ekhmaj Department Soil & Water Tripoli University

DOI:

https://doi.org/10.63359/eca9jp67

Keywords:

Hydrochemical Characteristics,, Seawater Intrusion Indicators, Fuzzy Logic, Ain Zara, Libya

Abstract

Coastal freshwater aquifer contamination by saline seawater is a significant threat to groundwater quality. This contamination is known as Seawater Intrusion (SWI). It leads to an increase in groundwater salinity, presenting both environmental and health risks. This study aims to assess seawater intrusion into the groundwater of the Ain Zara region, located south of Tripoli, by evaluating the relationship between Electrical Conductivity (EC) and Chloride (Cl-) concentrations in the groundwater, as well as Simpson’s Ratio (SR), the Groundwater Quality Index for Seawater Intrusion (GQISWI), the Seawater Mixing Index (SMI), and Hydrochemical Evolution Facies (HEF) diagrams. Additionally, a Fuzzy Seawater Intrusion Index (FSWI) model was developed, which uses fuzzy logic to assess the degree of seawater contamination in the aquifers. Forty groundwater samples were collected from wells in the study area in March 2023. The physico-chemical properties of the groundwater samples were Electrical Conductivity (EC), Total Dissolved Solids (TDS), pH, and major dissolved ions such as Sodium (Na+), Potassium (K+), Calcium (Ca2+), Magnesium (Mg2+), Chloride (Cl-), Bicarbonate (HCO3-), and Sulfate (SO42-). Additionally, the Potential Salinity (PS) was calculated. Four parameters were included in the FSWI model i.e.,TDS (mg/L), Cl- (mg/L), EC (µS/cm), and PS (mg/L).The results showed high variation coefficients for Chloride, Sodium, Calcium, and Total Dissolved Solids compared to the other ions, indicating the distinct chemical composition of the region's well waters. Additionally, the low variation coefficients for Bicarbonate and pH reflect the relative stability of these properties in the groundwater. The values of the seawater intrusion indicators revealed that the area is at risk of seawater intrusion, and it is following the same spatial distribution pattern. The developed FSWI model can reliably estimate the degree of seawater contamination in the groundwater. The obtained results highlight the urgent need for measures to mitigate this issue.

Author Biography

  • Ahmed Ibrahim Ekhmaj, Department Soil & Water Tripoli University

    جامعة طرابلس ، قسم التربة والمياه

    الدرجة العلمية استاد

References

خماج، أحمد إبراهيم و الرياني، عبدالرحمن أحمد. 2021 المقارنة بين طريقتي كريكنج الاعتيادية (OK) ومقلوب المسافة الوزنية (IDW) لتقدير تلوث مياه الخزانات الجوفية الضحلة بمياه البحر في مدينة طرابلس، ليبيا. المجلة السورية للبحوث الزراعية 7(5): 299-317.

شيخو طاهر ومحمود حاج عيسى وهادي ديوب. 2019. دراسة بعض الخصائص الفيزيائية والكيميائية لمياه نهر السن في حوض الساحل السوري. المجلة السورية للعلوم الزراعية. 6(3): 333-350.

وزارة الموارد المائية، 2021. بطاقة حصر مصادر المياه فرع المنطقة الغربية محطة ضخ عين زارة. صفخة: 3-9.

Al farrah. N and Walraevens. K. 2018, Groundwater Overexploitation and Seawater Intrusion in Coastal Areas of Arid and Semi-Arid Regions, Water 2018, 10, 143; doi:10.3390/w10020143.

Al farrah. N, Martens. K and Walraevens. K. 2011, Hydrochemistry of the Upper Miocene-Pliocene-Quaternary Aquifer Complex of Jifarah Plain, Nw-Libya. GEOLOGICA BELGICA (2011) 14/3-4:159 [2].

Antara. S, Udeshi. N, Varadan. V. 2014. Use of Fuzzy Logic in Determining Quality of Water. In.ternational Journal of Scientific & Engineering Research, Volume 5, Issue 9: 252-259.

APHA (1992) Standard Methods for Examination of Water and Wastewater. 18th Edition, American Public Health Association,Washington DC.

Appelo, C.A.J. and Postma, D. 2005. Geochemistry, Groundwater and Pollution, second ed. CRC Press, Boca Raton, Florida, USA.

Bourjila A, Dimane F, Ghalit M, et al.2023 An integrated seawater intrusion assessment in the Moroccan Ghiss-Nekor coastal aquifer using hydrogeochemical and geospatial techniques. Research Square; 2023. DOI: 10.21203/rs.3.rs-2118023/v4.

Cao. T, Han. D, Song. X. 2021. Past, present, and future of global seawater intrusion research: A bibliometric analysis. Journal of Hydrology Volume 603, Part A.

Cheng, A.D., Halhal, D., Naji, A. and Ouazar, D., 2000. Pumping optimization in saltwater‐intruded coastal aquifers.Water Resources Research, 36(8), pp.2155-2165.

Dieu, L.P.; Cong-Thi, D.; Segers, T.; Ho, H.H.; Nguyen, F.; Hermans, T. 2022 GroundwaterSalinization and Freshening Processes in the Luy River Coastal Aquifer, Vietnam. Water 2022, 14, 2358. https://doi.org/10.3390/.

Diouf, O. C., Weihermüller, L., Diedhiou, M., Beltoungou, E. Y. T. B., Dieng, N. M., Faye, S. C., Vereecken, H., & Faye, S. (2022). Groundwater Geochemistry and Saltwater Intrusion in the Dakar Coastal Area, Senegal. Journal of Geoscience and Environment Protection, 10, 45-64.

Drabbe, J., Ghyben, W.B., 1889. Nota in verband met de voorgenomen putboring nabij Amsterdam (Notes on the probable results of the proposed well drilling near Amsterdam). Tijdschrift van het Koninklijk Instituut van Ingenieurs. 8–22.

Edet, A., 2016. Hydrogeology and groundwater evaluation of a shallow coastal aquifer, southern Akwa Ibom State (Nigeria). Applied Water Science, 7, 2397-2412.

Ekhmaj, I.A.; Y. Ezlit; and and M. Elaalem (2014). The situation of seawater intrusion in Tripoli, Libya. 1- 6. International Conference on Biological, Chemical and Environmental Sciences (BCES-2014) June 14-15, 2014 Penang (Malaysia).

Ezzeldin, H.A. 2022. Delineation of Salinization and Recharge Sources Affecting Groundwater Quality Using Chemical and Isotopic Indices in the Northwest Coast, Egypt. Sustainability, 14, 16923. https://doi.org/10.3390/su142416923.

Ferguson, G. and Gleeson, T. 2012. Vulnerability of coastal aquifers to groundwater use and climate change. Nat. Clim. Change 2 (5): 342–345.

Fidelibus. M.D., Balacco. G, M.R. Alfio. M.R, et al., 2025. A chloride threshold to identify the onset of seawater/saltwater intrusion and a novel categorization of groundwater in coastal aquifers. Journal of Hydrology 653(1–4):132775.

Gayathri M N and Pieus. M T. 2022. Assessment of Ground Water Quality Using Fuzzy Based Water Quality Index. International Journal of Innovative Science and Research Technology (IJISRT). 7(3): 812-817.

Ghandour EIM, Khalil JB, Atta SA (1985) Distribution of carbonates, bicarbonates and pH values in groundwater of the Nile delta region, Egypt. Groundwater 23:35–41.

Ghiglieri, G., Carletti, A., Pittalis, D., 2012. Analysis of salinization processes in the coastal 26 carbonate aquifer of Porto Torres (NW Sardinia, Italy). J. Hydrol. 432-433. 27 Doi:10.1016/02.016.

Giménez-Forcada, E. (2010). Dynamic of Seawater Interface using Hydrochemical Facies Evolution Diagram (HFE-D). Ground Water. 48(2): 212-16.

Golden Software, LLC. 2011.Golden, CO 80402-0281 USA.

Gugulothu, S., Subbarao, N., Das, R. et al. Geochemical evaluation of groundwater and suitability of groundwater quality for irrigation purpose in an agricultural region of South India. Appl Water Sci 12, 142 (2022). https://doi.org/10.1007/s13201-022-01583-w.

Herzberg, A. 1901. Die wasserversorgung einiger Nordseebader. Gasbeleucht Wasserversorg 44, 842–844.

Jang. J.SR, Sun. C.T, Mizutani. E. 2004. Neuro-Fuzzy and soft computing. Taipi: Pearson Education, Chapter. 4.

Jeen S.W, Kang. J, Jung. H and Lee. J. 2021. Review of Seawater Intrusion in Western Coastal Regions of South Korea. Water 2021;13(6) 761. https://doi.org/10.3390/w13060761.

Jones, B., Vengosh, A., Rosenthal, E., Yechieli, Y., 1999. Geochemical investigations. Seawater Intrusion in Coastal AquifersdConcepts, Methods and Practices (pp. 51-71). Springer.

Klassen, J., Allen, D. M. and Kirste, D. (2014). Chemical Indicators of Saltwater Intrusion for the Gulf Islands, British Columbia, Final Report. Simon Fraser University.

Klir, G. J., and T. A. Folger. 1988 Fuzzy sets, uncertainty, and information. Englewood Cliffs, NJ: Prentice Hall.

Klenner , A. , Hartenfeller , M. , Schneider , P. , and Schneider , G. 2010. Fuzziness” in pharmacophore- based virtual screening and de novo design ’, Drug Discov. Today Technol. , 7 : 237 –244 .

Lakov, D. 1996. The first international discourse on fuzzy logic and the management of complexity, FLAMOC'96. Fuzzy Sets and Systems, volume 84, issue 1, pages 115.

Lekshmi, S.; Kani, M.K. Assessment of Seawater Intrusion Using Chemical Indicators. Int. J. Eng. Adv. Technol. 2017, 7, 100–108.

Lu. Chunhui and Werner. A. D. 2013. Timescales of seawater intrusion and retreat. Advances in Water Resources. Volume 59,Pages 39-51.

Luís. R, Cremasco . C. P, Luiz. R, Romanini. P. A, Gabriel. J. E, Leonardo, R. A. 2009. Determination of membership functions of the indices of water quality and of toxic and organoleptic substances. Presidente Prudente. 1 (1): 46-55.

Melloul, A.J. and Collin, M. 1998. A Proposed Index for Aquifer Water-Quality Assessment. Journal of Environmental Management, 54, 131-142.

Minitab, LLC. 2021. Minitab. Retrieved from https://www.minitab.com.

Moorthy, P.; Sundaramoorthy, S.; Roy, P.D.; Usha, T.; Dash, S.K.; Gowrappan, M.; Chokklingam, L. 2024 Evaluation of spatial and temporal dynamics of seawater intrusion in coastal aquifers of southeast India: Insights from hydrochemical facies analysis. Environ. Monit Assess. 196, 179.

Oladipo, J.O.; Akinwumiju, A.S.; Aboyeji, O.; Adelodun, A.A.2021. Comparison between fuzzy logic and water quality index methods: A case of water quality assessment in Ikare community, Southwestern Nigeria. Environ. Chall. 2021, 3, 100038.

Panteleit, B., Hamer, K., Kringel, R., Kessels, W., Schulz, H., 2011. Geochemical processes in the saltwaterefreshwater transition zone: comparing results of a sand tank experiment with field data. Environ. Earth Sci. 62 (1), 77-91.

Park, C.H. and Aral, M.M. Saltwater intrusion hydrodynamics in a tidal aquifer. J. Hydrol. Eng.2008, 13, 863–872.

Prusty, P., Farooq, S.H., Swain, D., Chandrasekharam, D., 2020. Association of geomorphic features with groundwater quality and freshwater availability in coastal regions. Int. J. Environ. Sci. Technol. https://doi.org/10.1007/s13762-020-02706-z.

Pulido-Leboeuf, P. (2004). Seawater intrusion and associated processes in a small coastal complex aquifer (Castell de Ferro, Spain). Applied geochemistry, 19(10), 1517-1527.

Raman Bai. V , Reinier. B and Mohan. S. 2009. Fuzzy Logic Water Quality Index and Importan of Water Quality Parameters. Air, Soil and Water Research. 2: 51–59.

Shi, L., Lu, C., Ye, Y., Xie, Y. and Wu, J. (2020). Evaluation of the performance of multiple-well hydraulic barriers on enhancing groundwater extraction in a coastal aquifer. Advances in Water Resources,144, 103704.

Simpson, T.R. 1946. Salinas basin investigation bull calif. div. water resource. Sacramento. 52. 230.

Sudaryanto. N. (2018) Ratio of major ions in groundwater to determine saltwater intrusion in coastal areas. Earth Environ Sci 118:5.

Suganthi, L., and Samuel.A. 2012..Energy models for demand forecasting—A review.. Renewable and sustainable energy reviews 16.2 (2012): 1223-1240.

Supriyadi, Khumaedi and Andya. P. P. 2017. Geophysical and hydrochemical approach for seawater intrusion in north Semarang, Central Java, Indonisia.. International Journal of GEOMATE, March, 2017, Vol. 12, Issue 31, pp. 134-140.

Taylor, R., Scanlon, B., Döll, P.et al. 2013. Ground water and climate change.Nature Clim Change 3, 322–329.

Timothy J. Ross. 2010. Fuzzy Logic with Engineering Applications. McGraw-Hill.

Todd, D.K. 1980 Groundwater Hydrology; Wiley: Hoboken, NJ, USA.

Tomaszkiewicz. M, Abou Najm. M. and El-Fadel. M. 2014. Development of a groundwater quality index for seawater intrusion in coastal aquifers. Environmental Modelling & Software 57: 13-26.

Trabelsi, N., Triki, I., Hentati, I.et al.2016. Aquifer vulnerability and seawater intrusion risk using GALDIT, GQISWI and GIS: case of a coastal aquifer in Tunisia. Environ Earth Sci 75, 669.

Verruijt, A. 1968. A note on the Ghyben-Herzberg formula. Hydrol. Sci. J. 13 (4): 43–46.

Washington State Department of Ecology (2005). Water Resource Inventory Area 06 Islands. Seawater Intrusion Topic Paper.

Zhang. B, Song. X, Han. D, Guo. Z, Xiao. G and Yang. J. 2013. Seawater Intrusion Degree Evaluation Based on Mathematical Statistics and Fuzzy Mathematics in Qinhuangdao Yangdai River Plain. (33) No. 3: 342-348.

Downloads

Published

29-04-2025

How to Cite

Identify of Seawater Intrusion Using Hydrochemical Approach and Fuzzy Logic for the Ain Zara, Libya. (2025). Libyan Journal of Ecological & Environmental Sciences and Technology, 7(1), A 41-55. https://doi.org/10.63359/eca9jp67

Similar Articles

1-10 of 149

You may also start an advanced similarity search for this article.